Solar-driven conversion of waste plastics into their building blocks

Photothermal catalysis, powered by clean solar energy, presents a highly efficient solution for converting waste plastic into valuable chemicals. This catalytic process utilizes the energy from sunlight to convert it into chemical energy. However, the development of photothermal catalysts with high conversion efficiency and catalytic activity poses significant challenges.

A recent groundbreaking achievement has been made by a team of researchers led by Prof. Jinxing Chen from Soochow University, China. They have successfully developed an integrated photothermal catalyst using c-ZIF-8 coated with a SiO₂ layer. This innovative approach focuses on enhancing catalytic activity by minimizing thermal radiation loss and maximizing the localized heating effect of the catalyst.

Their findings have been published in the Chinese Journal of Catalysis.

This study introduces a novel catalyst design approach that involves the synthesis of ZIF-8 nanoparticles using a template method. To create an integrated photothermal catalyst (c-ZIF-8@SiO₂), a layer of SiO₂ is coated onto the surface of ZIF-8, followed by a high-temperature carbonization treatment. The internal carbon material within the catalyst absorbs solar energy and generates heat, while the outer SiO₂ layer selectively allows penetration of solar light, which is then absorbed by the carbon core.

This design effectively reduces thermal radiation loss from the internal carbon core and enhances the local thermal effect during the photothermal catalysis process. Furthermore, the SiO₂ shell provides protection, resulting in high stability of the catalyst. Overall, this catalyst design strategy offers a universal method for enhancing the local thermal effect in photothermal catalysis and holds potential applications in the development of efficient photothermal catalytic systems.

The c-ZIF-8@25SiO₂ catalyst efficiently upcycles PET into valuable monomers when exposed to sunlight. The PET glycolysis experiment conducted under outdoor sunlight, as well as the selective recovery of PET from mixed plastics, demonstrates the promising applications of photothermal catalytic PET glycolysis. Photothermal catalysis not only contributes to energy conservation and emission reduction, promoting green and sustainable development, but also provides new ideas and methods for efficient chemical recycling of plastics.

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