The crystal structure, bulk electronic properties, and surface terminations of the TbV6Sn6 kagome metal are depicted in this research. Firstly, the crystal structure is showcased through top and side views of the unit cell. Moving on, the bulk electronic structure is examined along the Γ–K–M direction in the presence of spin-orbit coupling (SOC). The electronic states are color-coded based on the band and momentum-resolved density of states, with emphasis on the contributions highlighted in yellow. Furthermore, an in-depth analysis of specific regions of interest is provided, represented by the red boxes (1) and (2) in the previously mentioned diagram. The calculations with and without SOC are indicated by red and blue bands, respectively. Additionally, Sn 4d core level spectroscopy is conducted for both the kagome-terminated and Sn-terminated surfaces of TbV6Sn6. The results are presented in green and red curves, respectively. Moreover, ARPES Fermi surfaces are illustrated for the kagome and Sn terminations of TbV6Sn6, denoted as (e) and (f), respectively. Finally, the spectral function of the (001) surface Green’s function for the Sn termination in the absence of SOC is provided. The red boxes (1) and (2) correspond to those mentioned earlier.
These ground-breaking findings shed light on topological quantum materials and their potential in energy-saving electronics and future high-tech advancements. One notable property of these materials is the conduction of spin-polarized electrons on their surfaces, despite their non-conductive interior. To distinguish topological materials from conventional ones, scientists used to study their surface currents. However, the relationship between an electron’s topology and its quantum mechanical wave properties and spin has now been directly demonstrated through the photoelectric effect. This phenomenon involves the release of electrons from a material, such as metal, using light. By employing circularly polarized X-ray light, which possesses torque, the team was able to measure the signal from the quantum material based on the right- or left-handed polarization of the photons. This experiment can be likened to using 3D glasses to visualize the topology of electrons, as it makes their spin orientation visible.
This ground-breaking experiment was conducted by the Würzburg-Dresden Cluster of Excellence ct.qmat, which focuses on Complexity and Topology in Quantum Matter. The experimental setup relied on a particle accelerator, specifically a synchrotron, to generate the specialized X-ray light required for the experiment. The researchers spent three years on this project, starting from studying the kagome metal TbV6Sn6, a quantum material with a unique atomic lattice structure that resembles a Japanese basket weave. The team combined theoretical modeling and calculations on a supercomputer to simulate the results before carrying out the synchrotron experiment. The findings from the measurements aligned perfectly with the theoretical predictions, confirming the topology of the kagome metals.
The research paper detailing these findings is available on the Zenodo preprint server.
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